Factors controlling Macondo oil biodegraqdation on a rapidly eroding coastal headlands beach

Fourchon Beach, located along the southeast Louisiana coast, was affected by the oil leaking from the British Petroleum’s Deepwater Horizon Oil rig explosion in 2010. The oil, labeled MC252 oil, came ashore in a stable emulsion form, contaminating the sand, salt pan, marsh and mangroves along the beach. A unique oil form, labeled SSRB (small surface residue ball) was formed from the MC252 oil and a combination of environmental factors. The SSRB is an aggregate of sand and emulsified oil, and forms a large portion of the oil still present on the supratidal zone of Fourchon Beach. SSRBs have not been properly studied and their fate is largely unknown. For this research, various experiments were conducted to examine the biodegradability potential of SSRBs. First, an assessment of the subenvironments where the SSRBs were located was conducted. The environments appeared unfavorable for biodegradation to occur, with low organic matter and high salinities. Then, a characterization of the SSRBs’ physical and biochemical conditions was performed. Results indicated that their characteristics were closely dependent on the subenvironments in which they were located. Nonetheless; certain features pointing towards biodegradation were also found: microorganisms capable of degrading oil hydrocarbons and sources of nutrients and electron acceptors. Also, n-alkanes were substantially depleted in SSRBs sampled. Furthermore, a δ13C analysis in a respiration study indicated some biodegradation of crude oil, from respiration of oil instead of organic matter present. The implementation of these experiments helped identify and better understand the SSRBs and their biodegradability potential. This information obtained may offer us new solutions to challenges in environmental and waste cleanup. Also, help us determine how the oil spill has affected the supratidal area along Fourchon Beach, Louisiana and how best to proceed with cleanup efforts

Gradual transition from insulator to semimetal of Ca1−x_{1-x}Eux_{x}B6_{6} with increasing Eu concentration

The local environment of Eu$^{2+}$ ($4f^{7}$, $S=7/2$) in Ca$_{1-x}$Eu$_{x}$B$_{6}$ ($0.003\leqslant x\leqslant 1.00$) is investigated by means of electron spin resonance (ESR). For $x\lesssim 0.003$ the spectra show resolved \textit{fine} and \textit{hyperfine} structures due to the cubic crystal \textit{electric} field and nuclear \textit{hyperfine} field, respectively. The resonances have Lorentzian line shape, indicating an \textit{insulating} environment for the Eu$^{2+}$ ions. For $0.003\lesssim x\lesssim 0.07$, as $x$ increases, the ESR lines broaden due to local distortions caused by the Eu/Ca ions substitution. For $0.07\lesssim x\lesssim 0.30$, the lines broaden further and the spectra gradually change from Lorentzian to Dysonian resonances, suggesting a coexistence of both \textit{insulating} and \textit{metallic} environments for the Eu$^{2+}$ ions. In contrast to Ca$_{1-x}$Gd$_{x}$B$_{6}$, the \textit{fine} structure is still observable up to $x\approx 0.15$. For $x\gtrsim 0.30$ the \textit{fine} and \textit{hyperfine} structures are no longer observed, the line width increases, and the line shape is purely Dysonian anticipating the \textit{semimetallic} character of EuB$_{6}$. This broadening is attributed to a spin-flip scattering relaxation process due to the exchange interaction between conduction and Eu$^{2+}$ $4f$ electrons. High field ESR measurements for $x\gtrsim 0.15$ reveal smaller and anisotropic line widths, which are attributed to magnetic polarons and Fermi surface effects, respectively.Comment: Submitted to PR

B- and C-type low molecular weight glutenin subunits in tetraploid wheat germplasm

General knowledge acquisition entails the extraction of statistical regularities from the environment. At high levels of complexity, this may involve the extraction, and consolidation, of associative regularities across event memories. The underlying neural mechanisms would likely involve a hippocampo-neocortical dialog, as proposed previously for system-level consolidation. To test these hypotheses, we assessed possible differences in consolidation between associative memories containing cross-episodic regularities and unique associative memories. Subjects learned face-location associations, half of which responded to complex regularities regarding the combination of facial features and locations, whereas the other half did not. Importantly, regularities could only be extracted over hippocampus-encoded, associative aspects of the items. Memory was assessed both immediately after encoding and 48 h later, under fMRI acquisition. Our results suggest that processes related to system-level reorganization occur preferentially for regular associations across episodes. Moreover, the build-up of general knowledge regarding regular associations appears to involve the coordinated activity of the hippocampus and mediofrontal regions. The putative cross-talk between these two regions might support a mechanism for regularity extraction. These findings suggest that the consolidation of cross-episodic regularities may be a key mechanism underlying general knowledge acquisition

Site specific spin dynamics in BaFe2As2: tuning the ground state by orbital differentiation

The role of orbital differentiation on the emergence of superconductivity in the Fe-based superconductors remains an open question to the scientific community. In this investigation, we employ a suitable microscopic spin probe technique, namely Electron Spin Resonance (ESR), to investigate this issue on selected chemically substituted BaFe$_{2}$As$_{2}$ single crystals. As the spin-density wave (SDW) phase is suppressed, we observe a clear increase of the Fe 3$d$ bands anisotropy along with their localization at the FeAs plane. Such an increase of the planar orbital content interestingly occurs independently on the chemical substitution responsible for suppressing the SDW phase. As a consequence, the magnetic fluctuations combined with the resultant particular symmetry of the Fe 3$d$ bands are propitious ingredients to the emergence of superconductivity in this class of materials.Comment: 6 pages, 5 figure

Fermion soliton stars

A real scalar field coupled to a fermion via a Yukawa term can evade no-go theorems preventing solitonic solutions. For the first time, we study this model within General Relativity without approximations, finding static and spherically symmetric solutions that describe fermion soliton stars. The Yukawa coupling provides an effective mass for the fermion, which is key to the existence of self-gravitating relativistic solutions. We systematically study this novel family of solutions and present their mass-radius diagram and maximum compactness, which is close to (but smaller than) that of the corresponding Schwarzschild photon sphere. Finally, we discuss the ranges of the parameters of the fundamental theory in which the latter might have interesting astrophysical implications, including compact (sub)solar and supermassive fermion soliton stars for a standard gas of degenerate neutrons and electrons, respectively.Comment: 16 pages, 5 figure